In this work polyaniline (PANI) has been made through polymerization of aniline using emulsion polymerization technique. The polymerization is carried out in an emulsion comprising water and a non-polar or weakly polar organic solvent (Xylene) in the presence of the functionalized protonic acid dodecylbenzenesulphonic acid (DBSA). It is found that using the emulsion polymerization technique, conducting PANI-DBSA complexes can be produced that exhibit high molecular weight, good conductivity and high solubility in organic solvents in the electrically conducting state. Electrically conducting polyaniline PANI-DBSA prepared by an inverted emulsion polymerization in which DBSA played both roles of surfactant and dopant. Fourier transform infrared FTIR. spectroscopy for the PANI-DBSA showed the existence of hydrogen bonding between PANI and DBSA which indicates the existence of PANI. UV-Vis spectra was performed to check the doping level of DBSA. The electrical conductivity measurement, TGA test and measurement of viscosity was also studied in the book.

Dr. Alok Guptaas Professor in Chemical Engineering in M.N.I.T., Jaipur, since February 1999. Doctor of philosophy (PhD.) from Indian Institute of Technology, Kanpur. Master of Technology (M.Tech.) from Indian Institute of Technology, Kanpur.